Apparently there is no such thing as pure blue paint, from an RGB perspective. How odd! They all have high green values. (from http://www.easyrgb.com/en/match.php )pic.twitter.com/6q6AQ1W8Fp
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Well, you could compute a 3D space of the optimal spectra representing a chromaticity from 100% sRGB blue to white, and then pick the one that matches the brightness of 100%B in sRGB (which will be washed out)
I’m pretty sure sRGB (or any other gamut) doesn’t specify brightness.
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