Apparently there is no such thing as pure blue paint, from an RGB perspective. How odd! They all have high green values. (from http://www.easyrgb.com/en/match.php )pic.twitter.com/6q6AQ1W8Fp
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Colorimetry is hard, sure, but the difference I’m talking about is large enough that it doesn’t really matter.
The reason why there's no paint in pure sRGB corner colors is probably that it'd be too dark in normal lighting. If you only reflect a very narrow band of wavelengths as required, you're throwing away most of the spectrum. Things are always duller in reflective media.
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More like a curve of visual closeness vs. brightness, no?
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