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It's extremely unlikely that swallowing his stash would cause him to overdose that quickly. It has to be digested before it does anything and would be significantly weaker regardless.
I'm not an expert on opioid absorbtion but twenty minutes seems like a reasonable amount of time for an unknown quantity of orally ingested fentanyl to cause an overdose.
That's about the time of onset for most opiates, he would have had to have taken many times the lethal dose to drop dead of it that quickly.
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