Well the only sentient AIs that have ever existed in the MCU are Ultron, Vision, and that HYDRA guy who put his brain in a computer, right? Ultron died quickly and the HYDRA guy was kept secret. So Vision is the only one where these issues would pop up.
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The problem is that in biology, there are very rarely simple binaries. Even people who have undergone full cardiac arrest several hours ago have some transient metabolic activity, including in the brain. Where is death? Probably before that, but it's complicated.
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