Do colored lines correspond to dark lines for the same gas?
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The answer is YES as could be read in the interesting link in the tweet.
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Can it be used to find something that is not yet listed in the periodic table??
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It could, if there were naturally-occurring elements left to find. Helium was discovered that way. But uranium was the heaviest natural element still out there. All those since are artificial.
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Materials emit and interact with specific wavelengths of light in unique ways. Each type of spectra has particular uses: