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The argument is usually an in principle one to establish possibility (which does not actually get established), rather than a practical one
What kind of possibility? It doesn't seem like a bad argument if all you're trying to prove is physical possibility.
It's a map-territory error. We simulate atomic theory, not atoms. The above shows that water doesn't reduce to atomic theory.
I feel like saying the observed behavior of water "doesn't reduce" to theory is too strong of a claim if that is to say it wouldn't reduce to even an improved theory (agreed, not with present-day theory.) As for rules vs instances the problem there is more with nonlinearity/chaos
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