i think it's time to re-indoctrinate the youthpic.twitter.com/tdi0bFAYOA
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Well, translational, rotational and vibrational degrees of freedom are imho nothing that help understand the essence of electron density or core composition of different atoms.
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What? The radial and rotational degrees of freedom and the schrödinger equation are literally all there is to hydrogen quantum mechanically.. If you want to get into a core understanding of atomic structure you need to solve confinement first (a 1m$ prize awaits)
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