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I wonder though if it's an Android problem, or a Google IPv6 problem. You can't set the connectivity check endpoint on either iOS or Android, so it's hard to tell. The network trace at the end is strange, though.
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You can set Android's connectivity check endpoints via the global settings captive_portal_https_url, captive_portal_http_url, captive_portal_fallback_url and captive_portal_other_fallback_urls. These aren't exposed in the standard Settings app UI but they can be set via adb.
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